Telluric acid

 ( Hydroxides ) 

Telluric acid, or more accurately Ortho acid acid, is a chemical compound with the chemical formula , often written as . It is a white crystalline solid made up of octahedral molecules which persist in aqueous solution. In the solid state, there are two forms, rhombohedral and monoclinic, and both contain octahedral molecules, containing one hexavalent tellurium (Te) atom in the +6 oxidation state, attached to six hydroxyl (–OH) groups, thus, it can be called tellurium(VI) hydroxide. Telluric acid is a weak acid which is polyprotic acid, forming tellurate salts with and hydrogen tellurate salts with weaker bases or upon hydrolysis of tellurates in water.Holleman, A. F.; Wiberg, E. "Inorganic Chemistry" Academic Press: San Diego, 2001. . It is used as tellurium-source in the synthesis of oxidation catalysts.

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Preparation Telluric acid is formed by the oxidation of tellurium or tellurium dioxide with a powerful oxidising agent such as hydrogen peroxide, chromium trioxide or sodium peroxide.

Crystallization of telluric acid solutions below 10 °C gives telluric acid tetrahydrate . It is an oxidising agent, as shown by the electrode potential for the reaction below, although it is kinetically slow in its oxidations.

, E^o = +1.02 V

Chlorine, by comparison, is +1.36 V and selenous acid is +0.74 V in oxidizing conditions.

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Properties and reactions

The anhydrous acid is stable in air at 100 °C but above this it dehydrates to form polymetatelluric acid, a white hygroscopic powder (approximate composition ), and allotelluric acid, an acid syrup of unknown structure (approximate composition ).

Typical salts of the acid contains the anions and . The presence of the tellurate ion has been confirmed in the solid state structure of .

(2025). 9780131755536, Pearson. ISBN 9780131755536

Strong heating at over 300 °C produces the α crystalline modification of tellurium trioxide, α-. Reaction with diazomethane gives the hexamethyl ester, .

Telluric acid and its salts mostly contain hexacoordinate tellurium. This is true even for salts such as magnesium tellurate, , which is isostructural with magnesium molybdate and contains octahedra.

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Other forms of telluric acid

Metatelluric acid, , the tellurium analogue of sulfuric acid, , is unknown. Allotelluric acid of approximate composition , is not well characterised and may be a mixture of and .

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Other tellurium acids

Tellurous acid , containing tellurium in its +4 oxidation state, is known but not well characterised. Hydrogen telluride is an unstable gas that forms hydrotelluric acid upon addition to water.

Categories: Hydroxides, Tellurates, Oxidizing Acids, Chalcogen Oxoacids

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